Find the reagents, standards, coulometric kf titrators, and titrator accessories you need for measuring very low water content less than 2% in liquid and gaseous samples. Karl fischer titration is a classic titration method in analytical chemistry that uses coulometric or volumetric titration to determine trace amounts of water in a sample. All widely used titration parameters, including the ability to customize them, are incorporated in this unit. Mettler toledo v10s compact volumetric karl fischer titrator. History of karl fischer titration the milestones 1980 changed the world of kf titration 8 1935 karl fischer published a reagent for water determination consisting of iodine, so2, pyridine and methanol 1979 eugen scholz and helga hoffmann, riedelde haen, replaced pyridine by imidazole and invented hydranal reagents. It is a swift process which demands a minimal amount of sample preparation.
The addition of the solvent and the extraction of the titrated sample are carried out by the titration stand tm 235 kf at the push of a button. The titroline titrators offers full automation, and can run up to 72 samples unmonitored when paired with our tw series autosamplers. A titrator uses the analysis method wherein the sample is made to react with a reagent solution whose concentration is known, and from the volume of the reacted reagent, the. Karl fischer titration is simply a means to measure water content of samples. Karl fischer kf determination of water with kf drying. This article focuses on potentiometric and karl fischer titrators. Automatic potentiometic and karl fischer volumetric titration.
As opposed to other methods, such as drying ovens or infrared lamps, karl fischer titrators determine the actual water content in a sample, whereas other methods determine all volatile components that evaporate under the influence of heat. This may include acidbase, karl fischer kf, potentiometric, redox, gas phase, complexometric, or precipitation titration. Karl fischer titration is a method for moisture determination that is specific to water. Titrators for your samples the instruments in mettler toledos easyplus titration line are modern with a small footprint for use in a wide variety of basic applications. Voltametric kf titration back titration the automatic titrator is provided with twopoint auto calibration and standardization zero offset. C is generally between 10%100% for the instrument method endpoint. The mettler toledo v20s routine karl fischer titrator combines fast and precise water content determination with easy operation. Find out what metrohm has to offer for the monitoring of the water chemistry in thermal power plants, the wet chemical processing of solar cells and battery electrolytes, or electrochemical measurements of energy storage devices. Measuring priciple of karl fischer moisture titrators. Titrators for your samples the instruments in mettler toledos easyplus titration line are modern with a small footprint for. The coulometric karl fischer titration is concerned with the determination of traces of water from e. Repeat the same procedure by resetting the instrument to obtain 3 values for the factor of kf reagent which is not differing by 0.
Mettler toledo v20s compact volumetric karl fischer titrator. Ysi offers two titration product lines including autotitrators, manual titrators, dosing applications and solution preparation. Scope this method may be used for any kind of dried milk products, especially those containing. Sial survey 2003 alternative techniques weight loss upon drying most common alternative. Karl fischer coulometric titration explained and illustrated. The total moisture of a powder consists of free moisture content as well as crystal bounded water. Automatic potentiometric titrator karl fischer moisture titrator. A high current coulometric titrator for the karl fischer determination of water in which a diaphragm is not required between the electrodes of the iodinegenerating circuit. Stateoftheart performance features let you measure moisture content from low to high concentrations quickly and accurately. It can download results directly from the titrator through a serial port connection, or open result files previously saved to disk the results manager package contains all necessary cables, connections, installation cd and user manual. Classic karl fisher reagents contained pyridine, a noxious carcinogen, as the base. Mettler toledo titrators offer a broad range of possibilities to handle your data. About this document this document provides you with the information you need to get started with your mettler toledo titrator.
Kf volumetric titrator for karl fischer titrations hach. The linearity can be tested using solid water standards. For a comprehensive description of the instrument and its functions, refer to the operating instructions, supplied as. It is fitted for determining water in gases, liquids and solids. Its efficient, userfriendly design and portability make the aquamax kf unique from other such titration analysis instruments. The end point of the titration is recorded using bivoltametric indication.
Automatic titrator for the volumetric kf titration the titroline 7500 kf is the universalist for the volumetric karl fischer titration with a wide operating range of a few ppm 100% water content. Unlike other techniques, it can trace low levels of free, emulsified and dissolved. The measuring range of the coupled system kf titrator oven autosampler has to be checked to verify its accuracy and precision. These electrodes are designed to ensure that substantially only iodine is generated at the anode while minimizing conversion of iodine to iodide at the cathode. Karl fischer titrators titroline 7500 kf volumetric titrator. Samples with water content between 100 ppm and 100% are analyzed in single measurements or sample series with statistics. The traditional kf reagent contains iodine, sulfur dioxide in pyridine and methanol. Kf the limit or reasonable expected water content in sample, in% c the used volume, in %, of the capacity of the buret v the buret volume, in ml. The titrator automatically performs analyses with the help of predefined methods. It was invented in 1935 by the german chemist karl fischer. At the end of the titration, the display will show the result in mg of h2o 5 ml of kf reagent. Stoichiometrically, 1 mole of water will react with 1 mole of iodine, so that 1 milligram of water is equivalent to 10. On delivery of the instrument in the dl38 the kf standard method specified by us in the dl31 the kf standard method specified by us and 11 mettler methods are stored. For those who need to use the titrator outside of the laboratory and do not have.
With kf titration both free and bound water can be determined, e. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. The titroline 7750 combines the features of the potentiometric titrator titroline 7000 and the volumetric karl fischer titrator titroline 7500. The first consideration in choosing a titrator is to define the type of titration that is required.
May 30, 20 karl fischer titration is simply a means to measure water content of samples. Inexpensive coulometer including titration cell and generator electrode with diaphragm for water content determination down to trace levels. View online or download mettler toledo dl31 operating instructions manual. Titrator was subjected to technical modifications or to interventions in the form of attempted repair work by unauthorised personnel.
Pdf volumetric karl fischer titration researchgate. Karl fischer kf titration is the most popular water determination. This coulometer has become indispensable in many laboratories thanks to its reliability, its backlit graphical display, the multilanguage dialog and the simplicity of its operation. On a tight budget and looking for a reliable, easytouse volumetric karl fischer titrator. Labx titration the software wizard for easy and secure titrations. Kf or kft it remains the primary method of water content determination used worldwide by. Guide to potentiometric and karl fischer titrators.
Jarubol chaichana bureau of drug and narcotic department. The coulometric titrator helps in detecting free water, dissolved water, and emulsified water. When a titrastir stir plate is used, substitute or add the following optional apparatus. The basics of karl fischer titration karl fischer titration is an analytical technique to measure the amount of water contained in various samples, which may be solid, liquid or gaseous. The reagents most frequently used today are pyridinefree and contain. The instructions in this document refer to titrators running firmware version 5.
Product description aquamax kf plus titrators have been specifically designed for the determination of water content. Combining coulometry with the karl fischer method, aquamax kf titrators determine the water content of samples by measuring the amount of electrolysis current necessary to produce the required iodine this is an absolute technique which does not require the calibration of. With the new generation of mettler toledo compact volumetric and coulometric karl fischer titrators v20v30, c20c30 and excellence combined general and volumetric kf titrators t70 and t90, water determination has reached an unrivaled level of simplicity and security. Karl fischer titrator for volumetric water content. Karl fischer titration is the method of choice for water content determination. The aquamax kf provides an industry leading solution for companies interested in coulometric karl fischer titration analysis.
Aqv300 karl fischer volumetric titrator jm science. Scientific aquamax kf coulometric karl fischer titrator. Today, the titration is done with an automated karl fischer titrator. As opposed to other methods, such as drying ovens or infrared lamps, karl fischer titrators determine the actual water content in a sample, whereas other methods determine all volatile. Karl fischer titration is a classic titration method in chemical analysis that uses coulometric or volumetric titration to determine trace amounts of water in a sample.
Jarubol chaichana bureau of drug and narcotic department of. Hach kf instrument, sample stopper, sensor storage tubes, power supply, power cord, manual sold separately. In karl fischer kf volumetric determination, a titrant containing iodine is gradually added to the watercon taining sample until the water is completely displaced and free iodine can be detected in the titration solution. Samples from any industry with water content between 100 ppm and 100% are analyzed in single measurements or sample series with statistics. These electrodes are designed to ensure that substantially only iodine is generated at the anode while minimizing conversion of iodine to iodide at.
The mettler toledo v10s volumetric kf titrator is ideal for fast and precise water content determination with easy operation. The measuring range of the coupled system kf titratoroven autosampler has to be checked to verify its accuracy and precision. Titrator does not function properly, liquid has penetrated into the casing, the titroline. Manual titrators hach united kingdom overview hach. The ysi titroline 7500 kf volumetric titrator has multiple method ability. This method was originally developed in the 1930s by german chemist karl fischer.
Its straightforward operation and easy sample handling make stromboli an invaluable aid for many different industries such as pharmaceutical, polymer, petrochemical and specialty chemicals. Automatic titrator for exchangeable heads for potentiometry and kf the titroline 7750 is the allrounder for both potentiometric titration and volumetric kf titration. The titrastir stir plate holds the digital titrator during the titration and also stirs the sample at a constant speed, leaving the analyst free to detect the end point. The volumetric kf titrator is an easytooperate instrument for volumetric karl fischer titrations. Up to 4 titrators, at710b potentiometric titrators, mkv710b volumetric or mkh7102nd hybrid or additional mkc710b coulometric karl fischer moisture titrators can be connected and simultaneous measurement is possible. Metrohm autotitrator service manual eventually, you will totally discover a supplementary experience and carrying out by spending more cash. Pdf water determination by karl fischer titration researchgate. Manual kf titrino 701 pdf download pdf manual free. Chloride, silver nitrate method 10246 digital titrator, for gas and oil field shale waters.
Pdf the volumetric karl fischer titration is concerned with the water. The instrument is capable of displaying ph and mv of the sample, with temperature compensation. Mettler toledo dl31 operating instructions manual pdf download. New pyridine free kf reagents use amines and glycol ethers to replace the pyridine and methanol. A 1 d total moisture kf titration gea niro method no. When working with a hybrid titrator, the recommended sample sizes are the same as for coulometric titrations for low water contents 0. Volumetric kf titrator v10sv20sv30s user manual 30297193c 7182017 12. A karl fischer kf coulometric titrator is one of the most accurate methods. This coulometer has become indispensable in many laboratories thanks to its reliability, its backlit graphical display, the multi. The iodine in the presence of water is reduced to colorless hydrogen iodide. Water determination by karl fischer titration labicom. History of karl fischer titration karl fischer march 24, 1901 april 16, 1958 was a german chemist published a method in 1935 to determine trace amounts of water in samples. Kf titrator what is the meaning of karl fisher titration. Dont forget to order the karl fischer moisture content application pack hach pn ap0014.
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